Pakistan Research Repository

ISOLATION AND STRUCTURAL STUDIES ON THE CHEMICAL CONSTITUENTS OF BUXUS SPECIES

Ahmed, Dildar (1990) ISOLATION AND STRUCTURAL STUDIES ON THE CHEMICAL CONSTITUENTS OF BUXUS SPECIES. PhD thesis, University of Karachi, Karachi.

[img]HTML
13Kb

Abstract

Studies on the chemical constituents of the leaves of Buxus sempervirens have led to the isolation of seven new steroidal alkaloids and a new flavonoid glycoside. In addition, seven other alkaloids and two flavonoids have also been isolated. Modern spectroscopic techniques were employed to determine the structures of the compounds A new system of nomenclature has been established from Buxus alkaloids which gives considerable short and easy names. This has been described in the introduction section. I. New alkaloids 1. (-)-Sempervirone J. nat.prod. , 51, 783 (1988) 2. (-)-A-Buxenone Planta med., 54, 173 (1988) 3. (-)-cyclomicrobuxamine Fitoapia, 5, 439 (1989) 4. (+)-Acetylbuxanoldine Fitoterapia, 5, 439 (1989) 5. (+)-Semperviramidine Phytochemistry, 27, 2367 (1988) 6. (-)-Buxadienine Phytochemistry, 28, 1293 (1989) 7. (-)-31-Acetycyclomicrophylline-A Phytochemistry (accepted) II. Known alkaloids unreported from B. Semperviens 1. (-)-E-Cyclosufforbuxinine J.Nat.Prod. , 51 783 (1988) 2. (-)-A-Cycolsufforbuxinine 3. (+)-Buxaquaramarine Phytochemistry, 28, 1293 (1989) 4. (-)-16a-Acetoxybuxabenzamidienine Phytochemistry, 27, 2367 (1988) 5. (-)-31-Acetoxy-Na-benzoylbuxidienine Phytochemistry, 28, 1293 (1989) 6. (-)-Cyclomicrophylline-A J.Nat. Prod. (accepted) 7. (-)-Cyclomirobuxinine J.Nat.Prod. 51, 783 (1988) III Known alkaloids 1. (+)-Buxaminol-E 2. (-)-E-Buxenone Planta Med., 54, 173 (1988) 3. (+)-N-benzoylcycloxobuxine-F 4. (+)-N-Benzoyl-O-acetylcycloxobuxoline-F 5. (+)-Buxpsiine J.Nat.Prod. , (accepted) IV. A new flavonoid Glycoside, (-)-Galactobuxin J.Nat.Prod., (accepted) V. Known flavonoids 1.4’, 5-Dihydroxy-3,3’6,7-tetramethoxyflavone Planta Med., 54, 173 (1988) 2. Artemetin Planta Med., 54, 173 (1988).

Item Type:Thesis (PhD)
Uncontrolled Keywords:buxus species, buxus sempervirens, buxus alkaloids, alkaloids, flavonoids
Subjects:Physical Sciences (f) > Chemistry(f2)
ID Code:1088
Deposited By:Mr. Muhammad Asif
Deposited On:20 Feb 2007
Last Modified:04 Oct 2007 21:04

Repository Staff Only: item control page